simulation

Three-dimensional three-photon Stark spectroscopy of a single Rb Rydberg atom in an ultrahigh-vacuum glass cell with eight electrodes

Curator's Take

AI Commentary

This article shows how an eight‑electrode glass cell can generate fully independent three‑dimensional DC fields while a three‑photon excitation scheme eliminates light‑shift complications, enabling precise Stark spectroscopy of a single Rb Rydberg atom. Accurate field calibration is a bottleneck for neutral‑atom quantum processors and analog simulators because Rydberg interactions are extremely sensitive to stray electric fields, so this work directly supports higher‑fidelity gates in large tweezer arrays. It builds on recent progress in scalable atomic‑array platforms by providing a practical method to compensate stray fields and verify field homogeneity across the array. The approach will still need engineering to integrate the electrode geometry into dense multi‑qubit chips, but it offers a clear route toward more reliable neutral‑atom quantum hardware.

— Mark Eatherly

Summary

Quantum computing and quantum simulation with ultracold neutral atoms require Rydberg excitation of individual atoms in atomic arrays. Rydberg states are extremely sensitive to external electric fields, therefore precise three-dimensional control of the electric field is essential. We performed a spectroscopic study of three-photon Rydberg excitation of a single Rb atom in an optical dipole trap in the presence of an external DC electric field. The field was generated by eight electrodes deposited on the inner surfaces of an ultrahigh-vacuum glass cell. The used three-photon scheme of laser excitation of Rydberg \textit{nP} states allows the Stark shift and the splitting of the resonances to be observed simultaneously, which simplifies calibration of the electric field. In addition, in the commonly used two-photon Rydberg excitation schemes, the light shifts can complicate accurate determination of the DC Stark shift, particularly when the external electric field is scanned across different spatial directions, and different Stark components are excited. These shifts are absent in the three-photon excitation scheme used in our experiment. We demonstrated the ability to independently tune the electric field along all three spatial directions and to compensate for stray electric fields. The measured three-photon spectra exhibit Stark shifts and splittings of the three-photon resonance that are in good agreement with theoretical calculations. These results are also of interest for Rydberg electrometry.